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The Historical Photograph Collection is largely comprised of materials created by or for the Mount Vernon Ladies' Association. Photographers primarily include staff members and contract photographers. The collection spans the 1930s to the 2000s and includes analog material made up of a variety of sizes of film negatives providing a visual history of the Mansion, outbuildings, tombs, grounds, events, visitors, collection objects, personnel, restoration, and changes throughout the estate.

This collection consists of papers collected by various members of the Peter families. It includes letters from George Washington, letters of condolence to Martha Washington after George Washington's death, estate documents, Major George Peter's military papers, land plats and surveys, photo albums, letterbooks, and notebooks that tell of the life of this prominent family in Virginia and the City of Washington.

This collection contains letters to and from George Washington that have been aquired by the MVLA since 1858. For more information, see content note for individal items. The collection grows organically as new items are acquired.

This collection contains letters to and from Martha Washington that have been acquired by the MVLA since 1858. For more information, see content note for individual items. The collection grows organically as new items are acquired.

This collection consists of papers inherited and collected by Washington family descendants. Many were purchased in 1927 at auction to reunite Washington family correspondence. The collection includes correspondence, financial documents and legal documents that relate primarily to the Custis and Lewis families, but include other items related to Virginia history. Charles and Peter Chapin, the previous owners of this collection, descended from Eleanor Parke Custis and Lawrence Lewis through Esther Maria Lewis and Charles Chapin. This collection was originally assembled by Esther Maria Lewis Chapin who inherited some of the Washington/Custis papers, but was also an avid collector and brought back together family items that were being dispersed nationwide. This collection is an example of that effort; much of which was at auction in 1927 (Anderson Galleries, sale 2201, 28-29 November 1927).

Letters, chiefly 1765-1817, of the Blair, Banister, Braxton, Horner, and Whiting families. Correspondents include John Blair (1732-1800), Anne (Blair) Banister and Mary (Blair) Braxton Burwell Prescott. Many of the letters are written by women.

The Historical Photograph Collection is largely comprised of materials created by or for the Mount Vernon Ladies' Association. Some of the earliest photographs of the estate were created and sold to visitors by the Association as a means of income. Those efforts helped to establish an important collection of 19th century views. The collection spans the 1850s to 2000s and includes over 140 linear feet of analog material providing a visual history of the Mansion, outbuildings, tombs, grounds, events, visitors, collection objects, personnel, and changes throughout the estate.

This collection of historic manuscripts dates from 1607-1933, with the bulk of materials dating from 1738-1868. The correspondence, journals and diaries, legal and financial records, estate documents, and printed ephemera in the collection primarily relate to the Washington and Custis families, the Revolutionary War, and society life in antebellum Washington D.C. and Virginia.

This collection includes ephemera from 1796-1986, and contains a variety of formats that primarily relate to the portrayal of George Washington.

Portrait photographs of members of the Washington Family of Macon, Georgia and places connected with the family: Ellen Washington Bellamy, Judge Hugh Washington (brother of Ellen Washington Bellamy), Colonel James H.R. Washington with an autograph, home of Colonel H.R. Washington, family lot in Rose Hill Cemetery, and Washington Memorial Library.