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Collection contains correspondence from 1783-1831, of James Monroe written from Richmond, Virginia while serving time as governor, Paris while minister to France, London while minister to Great Britain, from Washington, D. C. while Secretary of State, Secretary of War, and from Loudoun County, Virginia after serving as President. Also included is a penciled sketch of Monroe by John Vanderlyn. Subjects covered in the collection include diplomatic service, education (advice to his nephew), United States foreign relations with France and Great Britain; the Missouri Compromise; and slavery. Among the correspondents are John Quincy Adams, John C. Calhoun, Henry Lee, John Marshall, Timothy Pickering, St. George Tucker and Monroe's uncle, Joseph Jones and his nephew James Monroe.

Prints and engravings removed from 18th century but mostly 19th century books or periodicals. Most prints cannot be matched with the book from which it came or the date. The location of the subject matter of each print or engraving is the primary criterion used in the organization of the collection.

Richard G. Joynt's collection of British manuscripts, from the 15th to the 20th century, of 88 letters and documents, 41 cut signatures, and many book engravings. The authors and signatures include kings, queens, prime ministers, nobles, military officers, authors, and other dignitaries. Personal matters, military orders and letters, religion, treaties, politics, intrique, and much more are covered in these letters, often interwoven with current events.

This collection includes four glass plate negatives, a sketch of Andrew Alexander, a letter signed by Andrew Alexander, and a letter dated 1796 from William C. Anderson to Francis Thomas.