- Blair, Banister, Braxton, Horner, Whiting Papers, 1760/1890, bulk 1765/18171
- Chapin collection of Washington & Custis family documents, 1758/18293
- Ellen Washington Bellamy Collection, 1860/19041
- Esther Maria Lewis Chapin collection of Washington family documents, 1743/18523
- George Washington collection, 1654/179910
- Historic ephemera collection, 1796/19867
- Historic manuscript collection, 1601/193314
- Historical Photograph Collection, 1850/201013
- Martha Washington collection, 1761/1802102
- Mount Vernon Black and White Film Collection, 1933/20054
- Page Family Papers, 1777/18221
- Peter family papers, 1722/193255
- Robert Waldsmith Collection of stereographs and cabinet cards, 1856/19813
- Sarah Tracy Collection, 1859/18683
- Washington and His Wife1