- Audio Visual Collection, 1928/20153
- Barbara Lustbader New York City playbills collection, 1957/20123
- Barnette Collection, Lawyer, Businessman, Educator, Philanthropist, and Chairman Emeritus of Bethlehem Steel Corporation, 1905/20203
- Benjamin L. Wigfall Artist Archives and Mary Carter Wigfall Personal Papers, 1880/202328
- Beverly Willis Architectural Collection, 1954/19993
- Blacksburg Baptist Church Records, 1894/20071
- Board of Visitors Records, 1920/20105
- Bob Bersson Papers, 1981/20172
- Breece D'J Pancake papers, 1973/20131
- Bruton Parish Church (Williamsburg, Va.) records, 1662/2010, bulk 1900/20002
- Calvert Walke Tazewell Papers, 1900/19971
- Carolyn Rhodes Papers, 1924/20196
- Carter/Cash Family Collection, 1940/20092
- Central Virginia gay and lesbian publications collection, 1987/20057
- Charles Lietwiler transportation collection, 1903/20052