- Alexandria Black Family Reunion Digital Collection, 1937/20054
- Alexandria Gazette I (MS331), 1942/19961
- Alexandria History Collection (MS240), 1767/200814
- Alexandria Hospital School of Nursing records, 1894/19871
- Alexandria Library Board Records (MS416), 1937/20208
- Alexandria Library Company Records (MS002), 1794/200720
- Alexandria Library Records (MS098), 1937/20139
- Alexandria Recital Series Papers (MS312), 1980/20023
- Alexandria, Virginia City Records (MS019), 1750/1983, bulk 1825/18751
- Alfonso García Robles papers, 1978/19882
- Alfred A. Bolton, Papers regarding History of Management and Other Material, 1900/200737
- Alfred C. Payne Collection, 1917/200354
- Alice Cartledge Cornett, Journalist, Papers, 1945/2017, bulk 1973/19921
- Alice Huffman Bugel Collection (Eighth Evacuation Unit Hospital), 1942/20001
- Alice McMechen, Collector, Papers of Artist Alvena V. Seckar, 1945/20083