- Ayre Family Collection, 1871/18991
- Bailey-Law Collection, 1825/197122
- Baldwin Family Letters, 1861/18972
- Battle of Cedar Creek Print, 18901
- Battle of Cedar Creek, 18902
- Battle of Chickamauga, 18901
- Baughman Family Papers, 1837/19688
- Beattie Family University Memorabilia, 1875/19591
- Bedford, Virginia, Auction Ledger, 1889/18901
- Bell, Kent, Cloyd, Withrow Family Collection, 1780/199843
- Benjamin Huddle Diary, 1861/20062
- Bert T. Wilson Papers, 1889/19262
- Bigler-Sessler-John Family Papers, 1752/19253
- Black, Kent, and Apperson Family Papers, 1779/198425
- Blacksburg [Virginia] Presbyterian Church Land Deeds, 1850/19242