- Beebe collection of Washington family papers, 1818/1861, bulk 1840/18504
- Elizabeth Bordley Gibson collection, 1794/18511
- Esther Maria Lewis Chapin collection of Washington family documents, 1743/18523
- Geo. Gregory Smart collection of Washington and Mount Vernon ephemera, 1793/201710
- Harrison H. Dodge Papers, 1816/19363
- Historic ephemera collection, 1796/19865
- Historic manuscript collection, 1601/193323
- Historic map collection, 1675/19711
- Historic newspapers collection, 1757/195712
- Historical Photograph Collection, 1850/20101
- Jane Charlotte Blackburn Washington and John Augustine Washington III correspondence, 1837/186112
- John Augustine Washington III and Eleanor Love Selden correspondence, 1842/186015
- John Augustine Washington III and Mount Vernon Ladies' Association (MVLA) collection, 1834/19577
- John Augustine Washington III and family papers, 1789/199427
- Land Records of the MVLA, 1858/20061