- W. Jett Lauck papers, 1900/19522
- W. Wilson Notebook, 1755/17992
- Wade Hampton Frost papers, 1880/19844
- Waller family papers, 1677/19651
- Wallpaper collection, 1757/18401
- Waring Family Papers, 1776/17802
- Washington and Lee University and Regional Virginia History Research Collection, 1609/20164
- Watts family papers-addition, 1786/19501
- Wayne Rickert collection of founders' autographs, 1770/18315
- Webb-Prentis Family Papers
1770-190829
- Webb-Prentis Family Papers,
1735-19425
- Welch Family Account Books, 1767/18801
- Welton Family Papers, 1770/19281
- West Virginia Land Grants Records, 1748/19125
- West Virginia Naturalization Records, 1814/19911