- Racial and Ethnic Ephemera Collection, 1778/20051
- Randolph Lytton historic Washington, D.C. postcards and photographs collection, 1905/19681
- Rev. Samuel Huntting Sayre, Jr. Papers, 1874/1989, bulk 1920/19601
- Roane Family Papers, 1880/1973, bulk 19501
- Robert Truax Washington, D.C. transportation collection, 1880/19851
- Ryland Correspondence Collection, 1843/19881
- Sarah McCulloh Lemmon Scrapbook, 1914/19911
- Shaver and Schaeffer Family Collection, 1872/19771
- Stephens and Yount Family Papers, 1812/19951
- Thomas L. Williams collection, 1940/19901
- VMI postcards, 1910/19701
- Williamsburg (Va.) Area Ephemera Collection, 1858/20151
- Wine Family Papers, 1885/20011