- Carrie Bishop Scrapbook, 1914/19181
- Charter Day collection, 1859/20221
- Commencement Exercises collection, 1831/20241
- Ephemera Collection, 1800/20141
- Geo. Gregory Smart collection of Washington and Mount Vernon ephemera, 1793/20171
- Guy Family Papers, 1900/19881
- James Madison, Sr. Papers, 1792/19311
- John Tyler, Jr. Papers, 1800/19281
- Kathleen Harless Scrapbook, 1911/19161
- Matthew Whaley School Collection, 1850/2012, bulk 1880/19601
- Mr. and Mrs. Donald W. Davis Collection, 1911/1994, bulk 1911/19441
- Myers-Burrage-Graham papers (I), Group A, 1776/19251
- Schuyler Otis Bland Papers, 1862/19501
- Shaw Family Papers, 1900/19631
- Thelma Pedersen Collection, 1899/19881