- Adam Empie Papers, 1811/2004, bulk 1811/18501
- Adam Empie letters, 1833/18371
- Alumni Association Records, 1833/2014, bulk 1950/20051
- Anonymous Scrapbook, 1885/18901
- Archibald C. Peachy Letter, 18481
- Archibald Woods Papers, 1777/1846, bulk 1783/18461
- Armistead-Cocke Papers, 1680/19171
- B. Davenport & Co. Ledger, 1841/18611
- B. T. Owen Letter to Sally Atkinson, 18401
- Benjamin Crowninshield Papers, 18041
- Benjamin H. B. Hubbard Report of Scholarship, Application and Conduct, 18601
- Benjamin Irby Student Paper, 18401
- Benjamin Stoddert Ewell Papers, 1784/1934, bulk 1830/18921
- Bishop James Madison Collection, 1776/18071
- Bishop James Madison Letter to James Breckenridge, 1805 December 20, 18051