- W. B. Osgood Diary, 1865/18671
- Warner Family Papers, 1899/19291
- Wasson-Cox Diary, 1826/1946, bulk 1826/18531
- William Harrison Smith Papers, 1934/19661
- William Sims Collection regarding Fugitive Slave Adam, 18051
- William and Mary Young Democrats Records, 1975/2013, bulk 1990/20121
- Williamsburg (Va.) Area Ephemera Collection, 1858/20151
- Williamsburg Area Council of Garden Clubs Records, 1961/2011, bulk 1975/19901
- Williamsburg Arts Council Scrapbook, 1967/19741
- Williamsburg Documentary Project, 1930/2015, bulk 2008/20151
- Winfree-McIlwaine Family Papers, 1875/1934, bulk 1880/18901